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When the pH is exactly at the pK a value, a buffer arises in which the deprotonated and protonated amino acids exist in equilibrium
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Stevens-Johnson Syndrome: An infrequent but unappealing side effect of certain drugs
Eaton DL et al
In aqueous solution, peptide bonds can hydrolyze, particularly at aspartate-proline and aspartate-glycine junctions, which are present in the BPC-157 sequence
B.KolteA
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